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Phase-pure BiFeO₃ produced by reaction flash-sintering of Bi₂O₃ and Fe₂O₃

ICMS

A. Perejon, P. E. Sanchez-Jiménez, M. J. Sayagues, R. Raj, L. A. Perez-Maqueda Journal of Materials Chemistry A 2018, Vol. 6, 5356-5366

Mixed powders of Bi2O3 and Fe2O3 are shown to yield single-phase, dense nanostructured polycrystals of BiFeO3 in reaction flash sintering experiments, carried out by applying a field of 50 V cm−1 and with the current limit set to 35 mA mm−2. The furnace was heated at a constant rate with the reaction sintering taking place abruptly upon reaching 625 °C. Remarkably, an intermediate bismuth-rich phase of the oxide that forms just before reaching the flash temperature transforms, and at the same time sinters, into single-phase BiFeO3 within a few seconds after the onset of the flash. The BiFeO3 so produced is electrically insulating, a property that is critical to its applications. This one-step synthesis of single-phase polycrystals of complex oxides from their basic constituents, by reaction flash sintering, is a significant development in the processing of complex oxides, which are normally difficult to sinter by conventional methods.

 

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