Enhanced Dihydrogen Activation by Mononuclear Iridium(II) Compounds: A Mechanistic Study
The organometallic chemistry of 4d and 5d transition metals has been vastly dominated by closed-shell states. The reactivity of their metalloradical species is though remarkable, albeit yet poorly understood and with limited mechanistic investigations available. In...
Plasma assisted CO2 dissociation in pure and gas mixture streams with a ferroelectric packed-bed reactor in ambient conditions
Carbon dioxide decomposition is a challenging target to combat climate change. Nonthermal plasmas are advantageous for this purpose because they operate at ambient conditions and can be easily scaled-up. In this study, we attempt the CO2 splitting into CO and O2 in a...
A novel Multi-Phase Flash Sintering (MPFS) technique for 3D complex-shaped ceramics
This work demonstrates the first proof-of-concept of Multi-Phase Flash Sintering (MPFS). This novel technique essentially consists of applying a rotating electric field to the sample by means of a multi-phase voltage source as furnace temperature increases. Several...
Optoelectronic Devices Based on Scaffold Stabilized Black-Phase CsPbI3 Nanocrystals
The optoelectronic properties of lead halide perovskites are intimately related to their crystalline phase. For the case of cesium lead iodide (CsPbI3) several polymorphs meet the Goldschmidt tolerance factor, which determines their stability, and form broad band...