Cytochrome c1 exhibits two binding sites for cytochrome c in plants

Cytochrome c1 exhibits two binding sites for cytochrome c in plants

In plants, channeling of cytochrome c molecules between complexes III and IV has been purported to shuttle electrons within the supercomplexes instead of carrying electrons by random diffusion across the intermembrane bulk phase. However, the mode plant cytochrome c...
Boryl-Assisted Hydrogenolysis of a Nickel-Methyl bond

Boryl-Assisted Hydrogenolysis of a Nickel-Methyl bond

A stable Nickel(II) methyl complex containing a diphosphinoboryl (PBP) pincer ligand is described. Mechanistic studies on the hydrogenolysis of the Ni-Me bond suggest a metal ligand cooperation mechanism that involves the intermediacy of a σ-B‒H Ni(0) species that...
Pt vs. Au in water–gas shift reaction

Pt vs. Au in water–gas shift reaction

This work presents a comparison of the gold- and platinum-based catalysts behavior in the water–gas shift (WGS) reaction. The influence of the support, e.g., its composition and electronic properties, studied in detail by means of UV–Vis spectroscopy, of the metal...
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