Subnanometric Pt clusters dispersed over Cs-doped TiO2 for CO2 upgrading via low-temperature RWGS: operando mechanistic insights to guide an optimal catalyst design
The RWGS reaction is gathering momentum as an effective route for CO2 valorisation and given its endothermic nature the challenge lies in the design of active low-temperature catalysts. Herein we have designed two catalysts based on subnanometric Pt clusters providing...
Dynamic Kinetic Resolution of Indole-Based Sulfenylated Heterobiaryls by Rhodium-Catalyzed Atroposelective Reductive Aldol Reaction
A highly enantio- and diastereoselective dynamic kinetic resolution (DKR) of configurationally labile 3-aryl indole-2-carbaldehydes is described. The DKR proceeds via a Rh-catalyzed intermolecular asymmetric reductive aldol reaction with acrylate esters, with...
Effect of Connectivity on the Carrier Transport and Recombination Dynamics of Perovskite Quantum Dot
Quantum-dot (QD) solids are being widely exploited as a solution-processable technology to develop photovoltaic, light-emission, and photodetection devices. Charge transport in these materials is the result of a compromise between confinement at the individual QD...
Strong Ligth-Matter Coupling in Lead Halide Perovskite Quantum Dot Solids
Strong coupling between lead halide perovskite materials and optical resonators enables both polaritonic control of the photophysical properties of these emerging semiconductors and the observation of fundamental physical phenomena. However, the difficulty in...
Fluorinated Man9 as a high mannose mimetic to unravel its recognition by DC-SIGN using NMR
Lectins are capable of reading out the structural information contained in carbohydrates through specific recognition processes. Determining the binding epitope of the sugar is fundamental to understanding this recognition event. Nuclear magnetic resonance (NMR) is a...