Dynamic Kinetic Asymmetric Heck Reaction for the Simultaneous Generation of Central and Axial Chirality

Dynamic Kinetic Asymmetric Heck Reaction for the Simultaneous Generation of Central and Axial Chirality

A highly diastereo- and enantioselective, scalable Pd-catalyzed dynamic kinetic asymmetric Heck reaction of heterobiaryl sulfonates with electron-rich olefins is described. The coupling of 2,3-dihydrofuran or N-boc protected 2,3-dihydropyrrole with a variety of...
Phase-pure BiFeO3 produced by reaction flash-sintering of Bi2O3 and Fe2O3

Phase-pure BiFeO3 produced by reaction flash-sintering of Bi2O3 and Fe2O3

Mixed powders of Bi2O3 and Fe2O3 are shown to yield single-phase, dense nanostructured polycrystals of BiFeO3 in reaction flash sintering experiments, carried out by applying a field of 50 V cm−1 and with the current limit set to 35 mA mm−2. The furnace was heated at...
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