May 26, 2017 | Sin categoría
In this Communication, a synthetic route is demonstrated to obtain stabilized MAPbI3nanocrystals embedded in thin metal oxide films that display well-defined and adjustable quantum confinement effects over a wide range of 0.34 eV. Mesostructured TiO2 and SiO2 films...
Abr 26, 2017 | Artículos del Mes, Artículos del Mes, Artículos del Mes, Artículos del Mes, Artículos del Mes, Artículos del Mes
Regulation of mitochondrial activity allows cells to adapt to changing conditions and to control oxidative stress, and its dysfunction can lead to hypoxia-dependent pathologies such as ischemia and cancer. Although cytochrome c phosphorylation—in particular, at...
Mar 26, 2017 | 2017, 2017, 2017, 2017, 2017
Complex [PtMe2 (PMe2 ArDipp2)] (1), which contains a tethered terphenyl phosphine (ArDipp2 =2,6-(2,6-(i) Pr2 C6 H3)2 C6 H3), reacts with [H(Et2 O)2 ]BArF (BArF(-) =B[3,5-(CF3 )2 C6 H3 ]4(-) ) to give the solvent (S) complex [PtMe(S)(PMe2 ArDipp2)](+) (2⋅S). Although...
Feb 26, 2017 | Sin categoría
We describe the synthesis, molecular, and electronic structure of the complex [Mo2Me2{μ-HC(NDipp)2}2] (2), that contains a dimetallic core with a Mo-Mo quadruple bond and features uncommon four-coordinate geometry and fourteen-electron count at each molybdenum atom...
Ene 26, 2017 | Sin categoría
The low electron count cationic platinum complex [Pt(ItBu’)(ItBu)][BArF], 1, interacts with primary and secondary silanes to form the corresponding σ-SiH complexes. According to DFT calculations the most stable coordination mode is the uncommon η1-SiH. The reaction of...
