Nov 27, 2014 | Sin categoría
A stable Nickel(II) methyl complex containing a diphosphinoboryl (PBP) pincer ligand is described. Mechanistic studies on the hydrogenolysis of the Ni-Me bond suggest a metal ligand cooperation mechanism that involves the intermediacy of a σ-B‒H Ni(0) species that...
Oct 27, 2014 | 2014, 2014, 2014, 2014, 2014, 2014
The accumulation of unfolded/misfolded proteins in the endoplasmic reticulum (ER) results in the activation of stress responses such as the unfolded protein response or the catabolic process of autophagy to ultimately recover cellular homeostasis. ER stress also...
Sep 27, 2014 | Sin categoría
T-cell intracellular antigen-1 (TIA-1) is a key DNA/RNA binding protein that regulates translation by sequestering target mRNAs in stress granules (SG) in response to stress conditions. TIA-1 possesses three RNA recognition motifs (RRM) along with a glutamine-rich...
Ago 27, 2014 | Artículos del Mes, Artículos del Mes, Artículos del Mes, Artículos del Mes, Artículos del Mes, Artículos del Mes
The production of H2 pure enough for use in fuel cells requires the development of very efficient catalysts for the water–gas shift reaction. Herein, a series of gold catalysts supported on ZnO-promoted CeO2–Al2O3 are presented as interesting systems for the...
Jul 27, 2014 | Sin categoría
This work presents a comparison of the gold- and platinum-based catalysts behavior in the water–gas shift (WGS) reaction. The influence of the support, e.g., its composition and electronic properties, studied in detail by means of UV–Vis spectroscopy, of the metal...
Jun 27, 2014 | Sin categoría
This work presents an evaluation of a high performance series of water gas shift (WGS) catalysts in the preferential CO oxidation reaction (PrOx) in order to examine the applicability of the same catalyst for both processes as a first step for coupling both reactions...
