Cysteine homeostasis plays an essential role in plant immunity

Cysteine homeostasis plays an essential role in plant immunity

Cysteine is the metabolic precursor of essential biomolecules such as vitamins, cofactors,antioxidants and many defense compounds. The last step of cysteine metabolism is catalysed by O-acetylserine(thiol)lyase (OASTL), which incorporates reduced sulfur into...
Highly Enantioselective Hydrogenation of b-Acyloxy and b-Acylamino a,b-Unsaturated Phosphonates Catalyzed by Rhodium Phosphane-Phosphite Complexes

Highly Enantioselective Hydrogenation of b-Acyloxy and b-Acylamino a,b-Unsaturated Phosphonates Catalyzed by Rhodium Phosphane-Phosphite Complexes

The enantioselective hydrogenation of b-(acyloxy)- and b-(acylamino)vinylphosphonates with rhodium catalysts based on chiral phosphane-phosphite ligands has been studied. In the case of the b-(acyloxy)vinylphosphonates, the reaction also produces an achiral...
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