Epimerization of glucose over ionic liquid/ phosphomolybdate hybrids: structure-activity relationship
The influence of the crystal structure and chemical nature of some ionic liquid/phosphomolybdate hybrids on their catalytic activity in the epimerization of glucose was studied. A clear evidence of structure–activity relationship was found. The inorganic part of the...
Selective catalytic synthesis of amino-silanesat part-per million catalyst loadings
Platinum(II) complex [Pt(ItBu0)(ItBu)][BArF4] (1a) is a highly active and selective catalyst in the dehydrocoupling of amines and silanes at part-per-million catalyst loadings (up to 10 ppm, 0.001 mol%), achieving the highest TON and TOF numbers reported in the...
Negative Regulation of Autophagy by Sulfide is Independent of Reactive Oxygen Species
Accumulating experimental evidence in mammalian, and recently plant, systems has led to a change in our understanding of the role played by hydrogen sulfide in life processes. In plants, hydrogensulfide mitigates stress and regulates important plant processes such as...
Optical analysis of CH3NH3SnxPb1−xI3 absorbers: a roadmap for perovskite-on-perovskite tandem solar cells
Organic–inorganic perovskite structures in which lead is substituted by tin are exceptional candidates for broadband light absorption. Herein we present a thorough analysis of the optical properties of CH3NH3SnxPb1−xI3films, providing the field with definitive...