Cooperative activation of X–H (X = H, C, O, N) bonds by a Pt(0)/Ag(I) metal-only Lewis pair
Metal-only Lewis pairs made of Pt(0)/Ag(I) combinations have been previously reported, but their cooperative reactivity remains unexplored. Here we demonstrate that these systems are capable of synergistically activating a wide variety of X–H (X = H, C, O, N) bonds,...
Base-Promoted, Remote C−H Activation at a Cationic (η5‐C5Me5)Ir(III) Center Involving Reversible C−C Bond Formation of Bound C5Me5
C−H bond activation at cationic [(η5-C5Me5)Ir(PMe2Ar′)] centers is described, where PMe2Ar′are the terphenyl phosphine ligands PMe2ArXyl2 and PMe2ArDipp 2. Different pathways are defined for the conversion of the five-coordinate complexes [(η5-C5Me5)-IrCl(PMe2Ar′)]+,...
Long distance electron transfer through the aqueous solution between redox partner proteins
En portadaLong distance electron transfer through the aqueous solution between redox partner proteins La producción de energía en el interior de las células vivas es fundamental para el correcto funcionamiento metabólico, hasta el punto de disponer de orgánulos...
HuR biological function involves dimerization and RNA binding by all three RNA recognition motifs
En portadaHuR biological function involves dimerization and RNA binding by all three RNA recognition motifs El cáncer es la segunda causa de mortalidad en el mundo. Desafortunadamente, es una enfermedad muy variable y que se manifiesta en tejidos muy diferentes...