Oxidative stress is tightly regulated by cytochrome c phosphorylation and respirasome factors in mitochondria
Respiratory cytochrome c has been found to be phosphorylated at tyrosine 97 in the postischemic brain upon neuroprotective insulin treatment, but how such posttranslational modification affects mitochondrial metabolism is unclear. Here, we report the structural...
Dynamic Kinetic Resolution of Heterobiaryl Ketones by Zinc‐Catalyzed Asymmetric Hydrosilylation
En portadaDynamic Kinetic Resolution of Heterobiaryl Ketones by Zinc‐Catalyzed Asymmetric Hydrosilylation Este artículo presenta una nueva estrategia para la síntesis enantioselectiva de compuestos con quiralidad axial. El desarrollo de métodos para la síntesis...
Isolation of a Cationic Platinum(II) s-Silane Complex
The platinum complex [Pt(ItBuiPr′)(ItBuiPr)][BArF] interacts with tertiary silanes to form stable (<0 °C) mononuclear PtII σ‐SiH complexes [Pt(ItBuiPr′)(ItBuiPr)(η1‐HSiR3)][BArF]. These compounds have been fully characterized, including X‐ray diffraction methods,...
Selective catalytic synthesis of amino-silanesat part-per million catalyst loadings
Platinum(II) complex [Pt(ItBu0)(ItBu)][BArF4] (1a) is a highly active and selective catalyst in the dehydrocoupling of amines and silanes at part-per-million catalyst loadings (up to 10 ppm, 0.001 mol%), achieving the highest TON and TOF numbers reported in the...