Selective catalytic synthesis of amino-silanesat part-per million catalyst loadings
Platinum(II) complex [Pt(ItBu0)(ItBu)][BArF4] (1a) is a highly active and selective catalyst in the dehydrocoupling of amines and silanes at part-per-million catalyst loadings (up to 10 ppm, 0.001 mol%), achieving the highest TON and TOF numbers reported in the...
Negative Regulation of Autophagy by Sulfide is Independent of Reactive Oxygen Species
Accumulating experimental evidence in mammalian, and recently plant, systems has led to a change in our understanding of the role played by hydrogen sulfide in life processes. In plants, hydrogensulfide mitigates stress and regulates important plant processes such as...
Optical analysis of CH3NH3SnxPb1−xI3 absorbers: a roadmap for perovskite-on-perovskite tandem solar cells
Organic–inorganic perovskite structures in which lead is substituted by tin are exceptional candidates for broadband light absorption. Herein we present a thorough analysis of the optical properties of CH3NH3SnxPb1−xI3films, providing the field with definitive...
Gold promoted Cu/ZnO/Al2O3 catalyst prepared from hydrotalcite precursors: Advanced materials for the WGS reaction
Outstanding catalysts for the water was shift reaction are reported in this work. The combination of gold nanoparticles with Cu/ZnO/Al2O3 prepared from hydrotalcite-like precursors leads to very promising systems for pure hydrogen production. Full CO conversion is...