Plasma assisted CO2 dissociation in pure and gas mixture streams with a ferroelectric packed-bed reactor in ambient conditions

Jun 25, 2022 | Uncategorized

Carbon dioxide decomposition is a challenging target to combat climate change. Nonthermal plasmas are advantageous for this purpose because they operate at ambient conditions and can be easily scaled-up. In this study, we attempt the CO2 splitting into CO and O2 in a...

Highly Anisotropic Organometal Halide Perovskite Nanowalls Grown by Glancing-Angle Deposition

Jun 9, 2022 | 2022, 2022, 2022, 2022, 2022, 2022, En portada OLD

En portadaHighly Anisotropic Organometal Halide Perovskite Nanowalls Grown by Glancing-Angle Deposition En este trabajo se han fabricado un nuevo tipo de nanoestructuras de perovskita híbridas de haluros organometálicos (MAPbI3) altamente anisotrópicas con morfología...

A novel Multi-Phase Flash Sintering (MPFS) technique for 3D complex-shaped ceramics

May 25, 2022 | Papers of the Month

This work demonstrates the first proof-of-concept of Multi-Phase Flash Sintering (MPFS). This novel technique essentially consists of applying a rotating electric field to the sample by means of a multi-phase voltage source as furnace temperature increases. Several...

Optoelectronic Devices Based on Scaffold Stabilized Black-Phase CsPbI3 Nanocrystals

Mar 25, 2022 | Uncategorized

The optoelectronic properties of lead halide perovskites are intimately related to their crystalline phase. For the case of cesium lead iodide (CsPbI3) several polymorphs meet the Goldschmidt tolerance factor, which determines their stability, and form broad band...

Asymmetric synthesis of dibenzo[b,d]azepines by Cu-catalyzed reductive or borylative cyclization

Feb 25, 2022 | Uncategorized

A copper-catalyzed asymmetric intramolecular reductive cyclization for the synthesis of dibenzo[b,d]azepines is described. Use of 2′-vinyl-biaryl-2-imines as substrates and in situ formed [CuI/(Ph-BPE)] as the catalyst enables the synthesis of 7-membered bridged...

Supported σ-Complexes of Li‒C Bonds from Coordination of Monomeric Molecules of LiCH3, LiCH2CH3 and LiC6H5 to MoMo Bonds

Jan 25, 2022 | Papers of the Month, Papers of the Month, Papers of the Month, Papers of the Month, Papers of the Month

LiCH3 and LiCH2CH3 react with complex [Mo2(H)2(μ-AdDipp2)2(thf)2] (1 thf) with coordination of two molecules of LiCH2R (R=H,CH3) and formation of complexes [Mo2{μ-HLi(thf)CH2R}2(AdDipp2)2], 5 LiCH3 and 5 LiCH2CH3 , respectively (AdDipp2=HC(NDipp)2; Dipp=2,6-iPr2C6H3 ;...