Reversible Hydride Migration from C5Me5 to RhI Revealed by a Cooperative Bimetallic Approach
The use of cyclopentadienyl ligands in organometallic chemistry and catalysis is ubiquitous, mostly due to their robust spectator role. Nonetheless, increasing examples of non‐innocent behaviour are being documented. Here, we provide evidence for reversible...
Ru-Ni/MgAl2O4 structured catalyst for CO2 methanation
Novel catalytic systems should be tested for the valorization of CO2 through the Sabatier reaction, since this process is gaining great importance within strategic sectors of the chemical industry. Therefore, this work explores the feasibility of structuring a...
Exploring protein phosphorylation by combining computational approaches and biochemical methods
Post-translational modifications of proteins expand their functional diversity, regulating the response of cells to a variety of stimuli. Among these modifications, phosphorylation is the most ubiquitous and plays a prominent role in cell signaling. The addition of a...
Second generation dendrimers with CS-E disaccharides as multivalent ligands for Langerin
Chondroitin sulfate type E (CS-E) is a sulfated polysaccharide that shows several interesting biological activities, such as the modulation of the neuronal growth factor signaling and its interaction with Langerin, a C-type lectin with a crucial role in the...
Chemistry and Electrocatalytic Activity of Nanostructured Nickel Electrodes for Water Electrolysis
Herein we have developed nanostructured nickel-based electrode films for anion exchange membrane water electrolysis (AEMWE). The electrodes were prepared by magnetron sputtering (MS) in an oblique angle configuration and under various conditions aimed at preparing...