An Evolutionarily Conserved DOF-CONSTANS Module Controls Plant Photoperiodic Signaling
The response to daylength is a crucial process that evolved very early in plant evolution, entitling the early green eukaryote to predict seasonal variability and attune its physiological responses to the environment. The photoperiod responses evolved into the complex...
Water-Promoted Generation of a Diazairida Homobarrelene by C—C Coupling Between an Iridacyclic Alkylidene and Acetonitrile
The stable cationic iridacyclopentenylidene [TpMe2Ir(=CHC(Me)=C(Me)CH2(NCMe)]PF6(A;TpMe2=hydrotris (3,5dimethylpyrazolyl)borate) has been obtained by α-hydride abstraction from the iridacyclopent-2-ene [TpMe2Ir(CH2C(Me)=C(Me)CH2)(NCMe)]. Complex A exhibits...
Design and realization of transparent solar modules based on luminescent solar concentrators integrating nanostructured photonic crystals
Herein, we present a prototype of a photovoltaic module that combines a luminescent solar concentrator integrating one-dimensional photonic crystals and in-plane CuInGaSe2 (CIGS) solar cells. Highly uniform and wide-area nanostructured multilayers with photonic...![A Diels–Alder Reaction Triggered by a [4 + 3] Metallacycloaddition](https://www.ciccartuja.es/wp-content/uploads/sites/4/2024/11/15_06.jpg)
A Diels–Alder Reaction Triggered by a [4 + 3] Metallacycloaddition
The TpMe2Ir(III) complex 1-OH2 (TpMe2 = hydrotris(3,5-dimethylpyrazolyl)borate), which contains a labile molecule of water and an iridium-bonded alkenyl moiety (−C(R)═C(R)–(R=CO2Me)) as part of a benzo-annulated five-membered iridacycle, reacts readily with the...