Characterization of a Paramagnetic, Mononuclear Pt (II)-Alkyl Complex Intermediate in Carbon-Halogen Bond Coupling Reaction

Characterization of a Paramagnetic, Mononuclear Pt (II)-Alkyl Complex Intermediate in Carbon-Halogen Bond Coupling Reaction

Addition of Br2 or I2 to 14-electron, cationic Pt(II)-alkyl complexes led to the formation of the corresponding carbon-halogen Pt(II) coupling products. Low temperature experiments with Br2 allowed us to isolate and characterize crystallographically a very unusual...
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