Jun 26, 2017 | 2017, 2017, 2017, 2017, 2017, 2017
In spite of the impressive efficiencies reported for perovskite solar cells (PSCs), key aspects of their working principles, such as electron injection at the contacts or the suitability of the utilization of a specific scaffold layer, are not yet fully understood....
May 26, 2017 | Uncategorized
In this Communication, a synthetic route is demonstrated to obtain stabilized MAPbI3nanocrystals embedded in thin metal oxide films that display well-defined and adjustable quantum confinement effects over a wide range of 0.34 eV. Mesostructured TiO2 and SiO2 films...
Apr 26, 2017 | Uncategorized
Regulation of mitochondrial activity allows cells to adapt to changing conditions and to control oxidative stress, and its dysfunction can lead to hypoxia-dependent pathologies such as ischemia and cancer. Although cytochrome c phosphorylation—in particular, at...
Mar 26, 2017 | Papers of the Month, Papers of the Month, Papers of the Month, Papers of the Month, Papers of the Month, Papers of the Month
Complex [PtMe2 (PMe2 ArDipp2)] (1), which contains a tethered terphenyl phosphine (ArDipp2 =2,6-(2,6-(i) Pr2 C6 H3)2 C6 H3), reacts with [H(Et2 O)2 ]BArF (BArF(-) =B[3,5-(CF3 )2 C6 H3 ]4(-) ) to give the solvent (S) complex [PtMe(S)(PMe2 ArDipp2)](+) (2⋅S). Although...
Feb 26, 2017 | Uncategorized
We describe the synthesis, molecular, and electronic structure of the complex [Mo2Me2{μ-HC(NDipp)2}2] (2), that contains a dimetallic core with a Mo-Mo quadruple bond and features uncommon four-coordinate geometry and fourteen-electron count at each molybdenum atom...
Jan 26, 2017 | Uncategorized
The low electron count cationic platinum complex [Pt(ItBu’)(ItBu)][BArF], 1, interacts with primary and secondary silanes to form the corresponding σ-SiH complexes. According to DFT calculations the most stable coordination mode is the uncommon η1-SiH. The reaction of...
